1996 Summer Olympics |
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| Air Pistol, 10 metres, Men | Friedhelm Sack | 8 | |
2000 Summer Olympics |
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| Air Pistol, 10 metres, Men | Friedhelm Sack | =34 | |
| Free Pistol, 50 metres, Men | Friedhelm Sack | =32 | |
2004 Summer Olympics |
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| Air Pistol, 10 metres, Men | Friedhelm Sack | =33 | |
| Free Pistol, 50 metres, Men | Friedhelm Sack | =41 | |
2008 Summer Olympics |
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| Trap, Women | Gaby Ahrens | 20 | |
2012 Summer Olympics |
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| Trap, Women | Gaby Ahrens | 22 | |
2016 Summer Olympics |
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| Trap, Women | Gaby Ahrens | 9 |