| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1996 Summer Olympics | Volodymyr Klychko | 1 | Gold |
| 2000 Summer Olympics | Oleksiy Mazikin | 5 | |
| 2004 Summer Olympics | Oleksiy Mazikin | =5 | |
| 2008 Summer Olympics | V'iacheslav Hlazkov | =3 | Bronze |
| 2020 Summer Olympics | Tsotne Rohava | =8 | |
| 2024 Summer Olympics | Dmytro Lovchynskyi | =9 |