| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1996 Summer Olympics | Franco Neto / Roberto Lopes | =9 | |
| Zé Marco / Emanuel | =9 | ||
| 2000 Summer Olympics | Zé Marco / Ricardo | 2 | Silver |
| Emanuel / José Loiola | =9 | ||
| 2004 Summer Olympics | Ricardo / Emanuel | 1 | Gold |
| Márcio / Benjamin | =9 | ||
| 2008 Summer Olympics | Márcio / Fábio | 2 | Silver |
| Ricardo / Emanuel | 3 | Bronze | |
| 2012 Summer Olympics | Alison Cerutti / Emanuel | 2 | Silver |
| Ricardo / Pedro Cunha | =5 | ||
| 2016 Summer Olympics | Alison Cerutti / Bruno Schmidt | 1 | Gold |
| Pedro Solberg / Evandro Oliveira Júnior | =9 | ||
| 2020 Summer Olympics | Alison Cerutti / Álvaro Filho | =5 | |
| Evandro Oliveira Júnior / Bruno Schmidt | =9 | ||
| 2024 Summer Olympics | Arthur Lanci / Evandro Oliveira Júnior | =5 | |
| André Stein / George Wanderley | =9 |
