| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1996 Summer Olympics | Sandra Pires / Jackie Silva | 1 | Gold |
| Mônica Rodrigues / Adriana Samuel | 2 | Silver | |
| 2000 Summer Olympics | Adriana Behar / Shelda | 2 | Silver |
| Sandra Pires / Adriana Samuel | 3 | Bronze | |
| 2004 Summer Olympics | Adriana Behar / Shelda | 2 | Silver |
| Ana Paula / Sandra Pires | =5 | ||
| 2008 Summer Olympics | Talita / Renata Ribeiro | 4 | |
| Ana Paula / Larissa | =5 | ||
| 2012 Summer Olympics | Juliana / Larissa | 3 | Bronze |
| Maria Elisa / Talita | =9 | ||
| 2016 Summer Olympics | Ágatha Rippel / Bárbara Seixas | 2 | Silver |
| Larissa / Talita | 4 | ||
| 2020 Summer Olympics | Ana Patrícia Ramos / Rebecca Silva | =5 | |
| Ágatha Rippel / Duda Lisboa | =9 | ||
| 2024 Summer Olympics | Duda Lisboa / Ana Patrícia Ramos | 1 | Gold |
| Carol Solberg / Bárbara Seixas | =9 |
