| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2000 Summer Olympics | Guo Jingjing / Fu Mingxia | 2 | Silver |
| 2004 Summer Olympics | Wu Minxia / Guo Jingjing | 1 | Gold |
| 2008 Summer Olympics | Guo Jingjing / Wu Minxia | 1 | Gold |
| 2012 Summer Olympics | He Zi / Wu Minxia | 1 | Gold |
| 2016 Summer Olympics | Shi Tingmao / Wu Minxia | 1 | Gold |
| 2020 Summer Olympics | Shi Tingmao / Wang Han | 1 | Gold |
| 2024 Summer Olympics | Chang Yani / Chen Yiwen | 1 | Gold |