| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2000 Summer Olympics | Li Na / Sang Xue | 1 | Gold |
| 2004 Summer Olympics | Lao Lishi / Li Ting | 1 | Gold |
| 2008 Summer Olympics | Wang Xin / Chen Ruolin | 1 | Gold |
| 2012 Summer Olympics | Chen Ruolin / Wang Hao | 1 | Gold |
| 2016 Summer Olympics | Chen Ruolin / Liu Huixia | 1 | Gold |
| 2020 Summer Olympics | Chen Yuxi / Zhang Jiaqi | 1 | Gold |
| 2024 Summer Olympics | Chen Yuxi / Quan Hongchan | 1 | Gold |
