| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2004 Summer Olympics | Dariya Nedashkovska | 21 | |
| 2008 Summer Olympics | Olena Khomrova | 8 | |
| Olha Kharlan | 13 | ||
| Halyna Pundyk | 29 | ||
| 2012 Summer Olympics | Olha Kharlan | 3 | Bronze |
| 2016 Summer Olympics | Olha Kharlan | 3 | Bronze |
| Alina Komashchuk | 15 | ||
| Olena Kravatska | 26 | ||
| 2020 Summer Olympics | Olha Kharlan | 17 | |
| 2024 Summer Olympics | Olha Kharlan | 3 | Bronze |
| Alina Komashchuk | 26 | ||
| Olena Kravatska | 32 |