| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2004 Summer Olympics | Liudmyla Holovchenko | 12 | |
| 2008 Summer Olympics | Yuliya Ostapchuk | 11 | |
| 2012 Summer Olympics | Yuliya Ostapchuk | 7 | |
| 2016 Summer Olympics | Yuliya Tkach | 9 | |
| 2020 Summer Olympics | Iryna Koliadenko | =3 | Bronze |
| 2024 Summer Olympics | Iryna Koliadenko | 2 | Silver |