| Date | 18 August 2016 — 9:20 | |
|---|---|---|
| Location | Riocentro Pavilhão 4, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Service Judge | Janelyn Fundal |  PHI |
| Umpire | Marcel Schmit |  SUI |
| Seed | Competitor | NOC | Games Won | Games Won | Game 1 | Game 2 | |
|---|---|---|---|---|---|---|---|
| 1 | Carolina Marín |  ESP | 2 | 2 | 21 | 21 | |
| 3 | Li Xuerui |  CHN | 0 | 0 | 14 | 16 |
| Carolina Marín | Li Xuerui | |
|---|---|---|
| Games Won | 2 | 0 |
| Game 1 | 21 | 14 |
| Game 2 | 21 | 16 |
