| Date | 11 August 2016 — 12:20 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Thomaz Bellucci |  BRA | 2 | 7 (12) | 6 | |
| 8 | David Goffin |  BEL | 0 | 6 (10) | 4 |
| Thomaz Bellucci | David Goffin | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 7 (12) | 6 (10) |
| Set #2 | 6 | 4 |
