| Date | 8 August 2016 — 12:33 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 10 | Roberto Bautista |  ESP | 2 | 7 (7) | 6 | |
| – | Paolo Lorenzi |  ITA | 0 | 6 (2) | 2 |
| Roberto Bautista | Paolo Lorenzi | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 7 (7) | 6 (2) |
| Set #2 | 6 | 2 |
