| Date | 9 August 2016 — 14:22 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Marijana Veljović |  SRB |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 3 | Rafael Nadal |  ESP | 2 | 2 | 6 | 6 | |
| – | Andreas Seppi |  ITA | 0 | 0 | 3 | 3 |
| Rafael Nadal | Andreas Seppi | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 3 |
