| Date | 6 August 2016 — 14:55 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 9) | |
| Chair Umpire | Pascal Maria |  FRA |
| Competitor | NOC | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|
| Andreas Seppi |  ITA | 2 | 6 | 3 | 7 (8) | |
| Illia Marchenko |  UKR | 1 | 3 | 6 | 6 (6) |
| Andreas Seppi | Illia Marchenko | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 6 | 3 |
| Set 2 | 3 | 6 |
| Set 3 | 7 (8) | 6 (6) |
