| Date | 6 August 2016 — 17:38 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | James Keothavong |  GBR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 13 | Philipp Kohlschreiber |  GER | 2 | 4 | 6 | 6 | |
| – | Guido Pella |  ARG | 1 | 6 | 1 | 2 |
| Philipp Kohlschreiber | Guido Pella | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 4 | 6 |
| Set #2 | 6 | 1 |
| Set #3 | 6 | 2 |
