| Date | 7 August 2016 — 17:35 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | James Keothavong |  GBR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 16 | Benoît Paire |  FRA | 2 | 3 | 6 | 6 | |
| – | Lukáš Rosol |  CZE | 1 | 6 | 3 | 4 |
| Benoît Paire | Lukáš Rosol | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 3 | 6 |
| Set #2 | 6 | 3 |
| Set #3 | 6 | 4 |
