| Date | 8 August 2016 — 16:38 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 8 | Roberto Bautista / David Ferrer |  ESP | 2 | 6 | 7 (7) | |
| – | Łukasz Kubot / Marcin Matkowski |  POL | 0 | 3 | 6 (5) |
Roberto Bautista / David Ferrer| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Roberto Bautista | ||||
| – | David Ferrer | ||||
| Team Totals | |||||
Łukasz Kubot / Marcin Matkowski| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Łukasz Kubot | ||||
| – | Marcin Matkowski | ||||
| Team Totals | |||||
