| Date | 8 August 2016 — 11:08 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 8) | |
| Chair Umpire | Mohamed El-Jennati |  MAR |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 5 | Florin Mergea / Horia Tecău |  ROU | 2 | 6 | 7 (11) | |
| – | Santiago González / Miguel Ángel Reyes |  MEX | 0 | 3 | 6 (9) |
Florin Mergea / Horia Tecău| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Florin Mergea | ||||
| – | Horia Tecău | ||||
| Team Totals | |||||
Santiago González / Miguel Ángel Reyes| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Santiago González | ||||
| – | Miguel Ángel Reyes | ||||
| Team Totals | |||||
