| Date | 7 August 2016 — 19:26 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Marijana Veljović |  SRB |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 6 | Marc López / Rafael Nadal |  ESP | 2 | 6 | 6 | |
| – | Robin Haase / Jean-Julien Rojer |  NED | 0 | 4 | 4 |
Marc López / Rafael Nadal| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Marc López | ||||
| – | Rafael Nadal | ||||
| Team Totals | |||||
Robin Haase / Jean-Julien Rojer| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Robin Haase | ||||
| – | Jean-Julien Rojer | ||||
| Team Totals | |||||
