| Date | 8 August 2016 — 13:37 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Paula Vieira |  BRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 15 | Elina Svitolina |  UKR | 2 | 2 | 6 | 1 | 6 | |
| – | Heather Watson |  GBR | 1 | 1 | 3 | 6 | 3 |
| Elina Svitolina | Heather Watson | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 6 | 3 |
| Set 2 | 1 | 6 |
| Set 3 | 6 | 3 |
