| | Top level | Event type
Singles, Women – Match #5
| Date | 8 August 2016 — 16:55 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Kader Nouni |  FRA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 3 | Garbiñe Muguruza |  ESP | 2 | 6 | 6 | |
| – | Nao Hibino |  JPN | 0 | 1 | 1 |
| Garbiñe Muguruza | Nao Hibino | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 6 | 1 |