| Date | 8 August 2016 — 11:03 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Carlos Bernardes |  BRA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 9 | Carla Suárez |  ESP | 2 | 7 (7) | 6 | |
| – | Ana Konjuh |  CRO | 0 | 6 (5) | 3 |
| Carla Suárez | Ana Konjuh | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 7 (7) | 6 (5) |
| Set 2 | 6 | 3 |
