| Date | 6 August 2016 — 15:10 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Carlos Bernardes |  BRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 15 | Elina Svitolina |  UKR | 2 | 2 | 6 | 6 | |
| – | Andrea Petkovic |  GER | 1 | 6 | 1 | 3 |
| Elina Svitolina | Andrea Petkovic | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 2 | 6 |
| Set #2 | 6 | 1 |
| Set #3 | 6 | 3 |
