| Date | 6 August 2016 — 12:26 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Gianluca Moscarella |  ITA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| – | Zhang Shuai |  CHN | 2 | 6 (4) | 6 | 7 (9) | |
| 12 | Timea Bacsinszky |  SUI | 1 | 7 (7) | 4 | 6 (7) |
| Zhang Shuai | Timea Bacsinszky | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 6 (4) | 7 (7) |
| Set #2 | 6 | 4 |
| Set #3 | 7 (9) | 6 (7) |
