| Date | 6 August 2016 — 11:19 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 8) | |
| Chair Umpire | Kelly Thomson |  GBR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Kristina Mladenovic |  FRA | 2 | 2 | 6 | 6 | |
| – | Aleksandra Krunić |  SRB | 0 | 0 | 1 | 4 |
| Kristina Mladenovic | Aleksandra Krunić | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 6 | 4 |
