| Date | 6 August 2016 — 14:20 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Jaume Campistol |  ESP |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Zheng Saisai |  CHN | 2 | 6 | 7 | |
| 4 | Agnieszka Radwańska |  POL | 0 | 4 | 5 |
| Zheng Saisai | Agnieszka Radwańska | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 4 |
| Set #2 | 7 | 5 |
