| Date | 7 August 2016 — 16:57 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Mohamed El-Jennati |  MAR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Caroline Garcia |  FRA | 2 | 2 | 6 | 6 | |
| – | Teliana Pereira |  BRA | 0 | 0 | 1 | 2 |
| Caroline Garcia | Teliana Pereira | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 6 | 2 |
