| Date | 7 August 2016 — 14:33 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 6) | |
| Chair Umpire | Damiano Torella |  ITA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Misaki Doi |  JPN | 2 | 2 | 6 | 6 | |
| – | Yaroslava Shvedova |  KAZ | 0 | 0 | 3 | 4 |
| Misaki Doi | Yaroslava Shvedova | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 4 |
