| Date | 12 August 2016 — 19:34 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Mohamed El-Jennati |  MAR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 5 | Timea Bacsinszky / Martina Hingis |  SUI | 2 | 2 | 5 | 7 | 6 | |
| 6 | Andrea Hlaváčková / Lucie Hradecká |  CZE | 1 | 1 | 7 | 6 | 2 |
Timea Bacsinszky / Martina Hingis| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Timea Bacsinszky | – | ||||
| – | Martina Hingis | – | ||||
| Team Totals | 7 | |||||
Andrea Hlaváčková / Lucie Hradecká| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Andrea Hlaváčková | – | ||||
| – | Lucie Hradecká | – | ||||
| Team Totals | 3 | |||||
