| Date | 9 August 2016 — 17:09 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Kader Nouni |  FRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 8 | Sara Errani / Roberta Vinci |  ITA | 2 | 6 | 6 | |
| – | Xu Yifan / Zheng Saisai |  CHN | 0 | 2 | 3 |
Sara Errani / Roberta Vinci| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Sara Errani | ||||
| – | Roberta Vinci | ||||
| Team Totals | |||||
Xu Yifan / Zheng Saisai| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Xu Yifan | ||||
| – | Zheng Saisai | ||||
| Team Totals | |||||
