| | Top level | Event type
Singles, Women – Match #25
| Date | 19 September 2000 | |
|---|---|---|
| Location | New South Wales Tennis Centre, Olympic Park, Sydney, New South Wales (Show Court #2) | |
| Chair Umpire | John Blom |  AUS |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 5 | Arantxa Sánchez Vicario |  ESP | 2 | 6 | 7 | |
| ITF | Li Na |  CHN | 0 | 1 | 5 |
| Arantxa Sánchez Vicario | Li Na | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 7 | 5 |