1988 Summer Olympics |
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| Flyweight, Men | Archer Fausto | =33 | |
| Bantamweight, Men | Alberto Machaze | =9 | |
| Welterweight, Men | Lucas Sinoia | =17 | |
1996 Summer Olympics |
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| Welterweight, Men | Lucas Sinoia | =17 | |
2012 Summer Olympics |
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| Light-Flyweight, Men | Juliano Máquina | =17 | |
2020 Summer Olympics |
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| Welterweight, Women | Alcinda Panguana | =5 | |
| Middleweight, Women | Rady Gramane | =5 |