| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1960 Summer Olympics | Therese Zenz / Ingrid Hartmann | 2 | Silver |
| 1964 Summer Olympics | Roswitha Esser / Annemarie Zimmermann | 1 | Gold |
| 1992 Summer Olympics | Ramona Portwich / Anke von Seck | 1 | Gold |
| 1996 Summer Olympics | Ramona Portwich / Birgit Fischer | 2 | Silver |
| 2000 Summer Olympics | Birgit Fischer / Katrin Wagner | 1 | Gold |
| 2004 Summer Olympics | Birgit Fischer / Carolin Leonhardt | 2 | Silver |
| 2008 Summer Olympics | Fanny Fischer / Nicole Reinhardt | 4 | |
| 2012 Summer Olympics | Franziska Weber / Tina Dietze | 1 | Gold |
| 2016 Summer Olympics | Franziska Weber / Tina Dietze | 2 | Silver |
| 2020 Summer Olympics | Sabrina Hering-Pradler / Tina Dietze | 8 | |
| Caroline Arft / Sarah Brüßler | 11 | ||
| 2024 Summer Olympics | Paulina Paszek / Jule Hake | =3 | Bronze |
| Lena Röhlings / Pauline Jagsch | 6 |
