| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Míriam Blasco | 1 | Gold |
| 1996 Summer Olympics | Isabel Fernández | =3 | Bronze |
| 2000 Summer Olympics | Isabel Fernández | 1 | Gold |
| 2004 Summer Olympics | Isabel Fernández | =5 | |
| 2008 Summer Olympics | Isabel Fernández | =9 | |
| 2012 Summer Olympics | Concepción Bellorin | =16 |