| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Catherine Fleury | 1 | Gold |
| 1996 Summer Olympics | Cathy Fleury-Vachon | =13 | |
| 2000 Summer Olympics | Séverine Vandenhende | 1 | Gold |
| 2004 Summer Olympics | Lucie Décosse | =7 | |
| 2008 Summer Olympics | Lucie Décosse | 2 | Silver |
| 2012 Summer Olympics | Gévrise Émane | =3 | Bronze |
| 2016 Summer Olympics | Clarisse Agbegnenou | 2 | Silver |
| 2020 Summer Olympics | Clarisse Agbegnenou | 1 | Gold |
| 2024 Summer Olympics | Clarisse Agbegnenou | =3 | Bronze |