| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2000 Summer Olympics | Steph Cook | 1 | Gold |
| Kate Allenby | 3 | Bronze | |
| 2004 Summer Olympics | Georgina Harland | 3 | Bronze |
| Kate Allenby | 8 | ||
| 2008 Summer Olympics | Heather Fell | 2 | Silver |
| Katy Livingston | 6 | ||
| 2012 Summer Olympics | Samantha Murray | 2 | Silver |
| Mhairi Spence | 21 | ||
| 2016 Summer Olympics | Kate French | 5 | |
| Samantha Murray | 8 | ||
| 2020 Summer Olympics | Kate French | 1 | Gold |
| Jo Muir | 14 | ||
| 2024 Summer Olympics | Kerenza Bryson | 9 | |
| Kate French | 19 |
