| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Kerstin Köppen / Kathrin Boron | 1 | Gold |
| 1996 Summer Olympics | Jana Thieme / Manuela Lutze | 5 | |
| 2000 Summer Olympics | Jana Thieme / Kathrin Boron | 1 | Gold |
| 2004 Summer Olympics | Peggy Waleska / Britta Oppelt | 2 | Silver |
| 2008 Summer Olympics | Annekatrin Thiele / Christiane Huth | 2 | Silver |
| 2012 Summer Olympics | Tina Manker / Stephanie Schiller | 9 | |
| 2016 Summer Olympics | Marie-Cathérine Arnold / Mareike Adams | 7 | |
| 2020 Summer Olympics | Annekatrin Thiele / Leonie Menzel | 11 |
