| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Dagmar Hase | 2 | Silver |
| Marion Zoller | 9 | ||
| 1996 Summer Olympics | Cathleen Rund | 3 | Bronze |
| Anke Scholz | 4 | ||
| 2000 Summer Olympics | Antje Buschschulte | 7 | |
| Cathleen Rund | 11 | ||
| 2004 Summer Olympics | Antje Buschschulte | =3 | Bronze |
| Nicole Hetzer | 11 | ||
| 2008 Summer Olympics | Christin Zenner | 34 | |
| 2012 Summer Olympics | Jenny Mensing | 15 | |
| 2016 Summer Olympics | Lisa Graf | 13 | |
| Jenny Mensing | 16 |