| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Summer Olympics | Goran Ivanišević / Goran Prpić | =3 | Bronze |
| 1996 Summer Olympics | Saša Hiršzon / Goran Ivanišević | =5 | |
| 2000 Summer Olympics | Mario Ančić / Goran Ivanišević | =17 | |
| 2004 Summer Olympics | Mario Ančić / Ivan Ljubičić | 3 | Bronze |
| 2008 Summer Olympics | Ivan Ljubičić / Marin Čilić | DNS | |
| 2012 Summer Olympics | Marin Čilić / Ivan Dodig | =5 | |
| 2016 Summer Olympics | Marin Čilić / Marin Draganja | =17 | |
| 2020 Summer Olympics | Nikola Mektić / Mate Pavić | 1 | Gold |
| Marin Čilić / Ivan Dodig | 2 | Silver | |
| 2024 Summer Olympics | Nikola Mektić / Mate Pavić | =17 |