| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1900 Summer Olympics | Charlotte Cooper / Reggie Doherty | 1 | Gold |
| 1920 Summer Olympics | Kitty McKane / Max Woosnam | 2 | Silver |
| Geraldine Beamish / Alfred Beamish | =8 | ||
| Dorothy Holman / Gordon Lowe | =14 | ||
| Winifred McNair / Noel Turnbull | =14 | ||
| 1924 Summer Olympics | Kitty McKane / Brian Gilbert | 4 | |
| Phyllis Covell / Leslie Godfree | =5 | ||
| 2012 Summer Olympics | Laura Robson / Andy Murray | 2 | Silver |
| 2016 Summer Olympics | Heather Watson / Andy Murray | =5 | |
| Johanna Konta / Jamie Murray | =9 | ||
| 2024 Summer Olympics | Heather Watson / Joe Salisbury | =9 |