| Date | 12 August 2016 — 14:59 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Jake Garner |  USA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 3 | Rafael Nadal |  ESP | 2 | 2 | 6 | 6 | |
| – | Thomaz Bellucci |  BRA | 1 | 6 | 4 | 2 |
| Rafael Nadal | Thomaz Bellucci | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 2 | 6 |
| Set #2 | 6 | 4 |
| Set #3 | 6 | 2 |
