| Date | 9 August 2016 — 11:10 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Carlos Bernardes |  BRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Yevgeny Donskoy |  RUS | 2 | 2 | 3 | 7 | 7 | |
| 7 | David Ferrer |  ESP | 1 | 1 | 6 | 6 | 5 |
| Yevgeny Donskoy | David Ferrer | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 3 | 6 |
| Set 2 | 7 | 6 |
| Set 3 | 7 | 5 |
| Tie-break 2 | 7 | 1 |
