| Date | 6 August 2016 — 14:26 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Carlos Ramos |  POR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 5 | Jo-Wilfried Tsonga |  FRA | 2 | 4 | 7 | 6 | |
| – | Malek Jaziri |  TUN | 1 | 6 | 5 | 3 |
| Jo-Wilfried Tsonga | Malek Jaziri | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 4 | 6 |
| Set #2 | 7 | 5 |
| Set #3 | 6 | 3 |
