| Date | 7 August 2016 — 15:06 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Carlos Ramos |  POR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 3 | Rafael Nadal |  ESP | 2 | 6 | 6 | |
| – | Federico Delbonis |  ARG | 0 | 2 | 1 |
| Rafael Nadal | Federico Delbonis | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 2 |
| Set #2 | 6 | 1 |
