| Date | 6 August 2016 — 17:35 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 9) | |
| Chair Umpire | Thomas Sweeney |  AUS |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Yevgeny Donskoy |  RUS | 2 | 2 | 6 | 6 | |
| – | Jan-Lennard Struff |  GER | 0 | 0 | 3 | 4 |
| Yevgeny Donskoy | Jan-Lennard Struff | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 4 |
