| Date | 6 August 2016 — 18:11 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 7) | |
| Chair Umpire | Jaume Campistol |  ESP |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Juan Mónaco |  ARG | 2 | 2 | 6 | 6 | |
| – | Mirza Bašić |  BIH | 0 | 0 | 2 | 2 |
| Juan Mónaco | Mirza Bašić | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 2 |
| Set 2 | 6 | 2 |
