| Date | 11 August 2016 — 15:35 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Emmanuel Joseph |  FRA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 6 | Marc López / Rafael Nadal |  ESP | 2 | 7 (7) | 7 (7) | |
| 7 | Daniel Nestor / Vasek Pospisil |  CAN | 0 | 6 (1) | 6 (4) |
Marc López / Rafael Nadal| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Marc López | ||||
| – | Rafael Nadal | ||||
| Team Totals | |||||
Daniel Nestor / Vasek Pospisil| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Daniel Nestor | ||||
| – | Vasek Pospisil | ||||
| Team Totals | |||||
