| Date | 8 August 2016 — 18:18 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Carlos Ramos |  POR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Fabio Fognini / Andreas Seppi |  ITA | 2 | 2 | 5 | 7 | 6 | |
| – | Thomaz Bellucci / André Sá |  BRA | 1 | 1 | 7 | 5 | 3 |
Fabio Fognini / Andreas Seppi| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Fabio Fognini | ||||
| – | Andreas Seppi | ||||
| Team Totals | |||||
Thomaz Bellucci / André Sá| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Thomaz Bellucci | ||||
| – | André Sá | ||||
| Team Totals | |||||
