| Date | 7 August 2016 — 17:49 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Marija Čičak |  CRO |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 3 | Marcelo Melo / Bruno Soares |  BRA | 2 | 2 | 6 | 7 | |
| – | Sanchai Ratiwatana / Sonchat Ratiwatana |  THA | 0 | 0 | 0 | 6 |
Marcelo Melo / Bruno Soares| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Marcelo Melo | – | ||||
| – | Bruno Soares | – | ||||
| Team Totals | 7 | |||||
Sanchai Ratiwatana / Sonchat Ratiwatana| Pos | Seed | Competitor | Tie-break 2 | |||
|---|---|---|---|---|---|---|
| – | Sanchai Ratiwatana | – | ||||
| – | Sonchat Ratiwatana | – | ||||
| Team Totals | 1 | |||||
