| Date | 12 August 2016 — 12:39 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Julie Kjendlie |  NOR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| – | Mónica Puig |  PUR | 2 | 6 | 1 | 6 | |
| 11 | Petra Kvitová |  CZE | 1 | 4 | 6 | 3 |
| Mónica Puig | Petra Kvitová | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 6 | 4 |
| Set #2 | 1 | 6 |
| Set #3 | 6 | 3 |
