| Date | 9 August 2016 — 11:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Miriam Bley |  GER |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 11 | Petra Kvitová |  CZE | 2 | 4 | 6 | 6 | |
| – | Yekaterina Makarova |  RUS | 1 | 6 | 4 | 4 |
| Petra Kvitová | Yekaterina Makarova | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 4 | 6 |
| Set #2 | 6 | 4 |
| Set #3 | 6 | 4 |
